Can you boot a DG31PR to WinPE 3.0?

I'm trying to save myself a whole bunch of headache by asking this question: will I be able to boot my DG31PR's to WindowsPE 3.0? That is, to the "Windows 8" PE environment?

I think I've found the right driver to use for the Realtek RTL8111B NIC, but what else will I need to attempt this?

Thanks.